The persistence length is the length scale over which a polymer’s tangent direction stays correlated — roughly, how far you can travel along the chain before thermal bending randomizes its orientation.

It ties the bending stiffness to thermal energy:

For double-stranded DNA, (about 150 base pairs). Below this length DNA behaves like a stiff rod; far above it, like a flexible entropic coil — the regime made tangible in the wlc-force-extension explorer, where sets the scale of the entropic restoring force.